primary, secondary and tertiary carbon

The chemical reactivity of alkyl halides is frequently discussed using alkyl halide classifications to help discern patterns and trends. A carbon is called primary if it has only one neighboring alkyl carbon atom, secondary if it has two and tertiary for three linked alkyl carbon atoms. don’t count. This corresponds with alkyl radical stability: tertiary radical species are more stable than secondary radical species, and secondary radical species are more stable than primary radical species—thus any single chlorination will favor substitution at the most substituted carbon. By increasing the number of adjacent carbon atom: methyl is the least stable carbocation

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